A man who is critically ill after being exposed to an unknown substance in Wiltshire is a Russian national convicted of spying for Britain.
Sergei Skripal, 66, was granted refuge in the UK following a "spy swap" between the US and Russia in 2010.
He and a woman, 33, were found unconscious on a bench at a shopping centre in Salisbury on Sunday.
Zizzi restaurant in Salisbury has been closed by police "as a precaution".
The substance has not been identified, but Public Health England said there was no known risk to the public's health.
Wiltshire Police are investigating whether a crime has been committed. They said the pair had no visible injuries but had been found unconscious at the Maltings shopping centre.
They have declared a "major incident" and multiple agencies are investigating. They said it had not been declared as a counter-terrorism incident, but they were keeping an "open mind".
Col Skripal, who is a retired Russian military intelligence officer, was jailed for 13 years by Russia in 2006 for spying for Britain.
He was convicted of passing the identities of Russian intelligence agents working undercover in Europe to the UK's Secret Intelligence Service, MI6.
Russia said Col Skripal had been paid $100,000 for the information, which he had been supplying from the 1990s.
He was one of four prisoners released by Moscow in exchange for 10 US spies in 2010, as part of a swap. Col Skripal was later flown to the UK.
He and the woman, who police said were known to each other, are both in intensive care at Salisbury District Hospital.
A number of locations in the city centre were cordoned off and teams in full protective gear used hoses to decontaminate the street.
The hospital advised people to attend routine operations and outpatient appointments unless they were contacted. It said its A&E department was open but busy because of the weather.
On the restaurant closure, police said Public Health England had reiterated the advice that there was no known risk to the wider public, but as a precaution advised that if people felt ill they should contact the NHS on 111.
"If you feel your own or another's health is significantly deteriorating, ring 999," police said.
Neighbours at Sergei Skripal's home in Salisbury say police arrived around 17:00 GMT on Sunday and have been there ever since.
They said he was friendly and in recent years had lost his wife.
The possibility of an unexplained substance being involved has drawn comparisons with the 2006 poisoning of Alexander Litvinenko.
The Russian dissident died in London in 2006 after drinking tea laced with a radioactive substance.
A public inquiry concluded that his killing had probably been carried out with the approval of the Russian President, Vladimir Putin.
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